Determination of cosmogenic ^(32)P and ^(33)P in environmental samples  

作　　者：CHEN Min YANG Zhi ZHANG Lei QIU Yusheng MA Qiang HUANG Yipu 

机构地区：[1]College of Ocean and Earth Sciences, Xiamen University [2]State Key Laboratory of Marine Environmental Science, Xiamen University

出　　处：《Acta Oceanologica Sinica》2013年第6期18-25,共8页海洋学报（英文版）

基　　金：The National Natural Science Foundation of China under contract No.41125020;a special scientific research project for public welfare supported by the State Oceanic Administration under contract No.2010050012-3

摘　　要：Understanding phosphorus dynamics in marine environment is of great importance, and appropriate trac- ers for phosphorus cycling in oceans are invaluable. In this study, two methods were developed for extrac- tion, purification, and determination of naturally occurring ^32p and ^33P in rainwater, marine plankton and sediments using both a low-level beta counter （LBC） and an ultra-low-level liquid scintillation spectrome- ter （LSS）. Blanks, chemical yields and counting efficiencies were quantified for both methods. The chemical purification of ^32P and ^33P separated by both procedures was validated by their decay curves. The absorber thickness of aluminum for LBC was assessed as 39.2 mg/cm2. ^32P and ^33P specific activities in some rain samples were determined by both methods and showed good consistent results. The advantage of the LSS over the LBC is apparent in its high counting efficiency and in determining samples with high concentration of stable phosphorus. However, when measuring environmental samples with low concentration of stable phosphorus, such as rainwater, both methods can be used and each has its distinct advantage.Understanding phosphorus dynamics in marine environment is of great importance, and appropriate trac- ers for phosphorus cycling in oceans are invaluable. In this study, two methods were developed for extrac- tion, purification, and determination of naturally occurring ^32p and ^33P in rainwater, marine plankton and sediments using both a low-level beta counter （LBC） and an ultra-low-level liquid scintillation spectrome- ter （LSS）. Blanks, chemical yields and counting efficiencies were quantified for both methods. The chemical purification of ^32P and ^33P separated by both procedures was validated by their decay curves. The absorber thickness of aluminum for LBC was assessed as 39.2 mg/cm2. ^32P and ^33P specific activities in some rain samples were determined by both methods and showed good consistent results. The advantage of the LSS over the LBC is apparent in its high counting efficiency and in determining samples with high concentration of stable phosphorus. However, when measuring environmental samples with low concentration of stable phosphorus, such as rainwater, both methods can be used and each has its distinct advantage.

关 键 词：^32p  ^33P RAINWATER PLANKTON SEDIMENTS 

分 类 号：P159[天文地球—天文学]