Studies on synergistic solvent extraction of rare earth elements from nitrate medium by mixtures of 8-hydroxyquinoline with Cyanex 301 or Cyanex 302  

作　　者：田苗苗 贾琼 廖伍平 

机构地区：[1]College of Chemistry,Jilin University [2]State Key Laboratory of Rare Earth Resource Utilization,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences

出　　处：《Journal of Rare Earths》2013年第6期604-608,共5页稀土学报（英文版）

基　　金：supported by National 973 Program of China(2012CBA01206);National Natural Science Foundation of China(51222404);the financial support from State Key Laboratory of Rare Earth Resource Utilization,Changchun Institute of Applied Chemistry(RERU2011006)

摘　　要：Synergistic solvent extraction of rare earth elements （REEs） from nitrate medium was investigated with mixtures of 8-hydroxyquinoline （HQ） and acidic organophosphorus extractants, bis（2,4,4-trimethylpentyl） dithiophosphinic acid （Cyanex 301） and bis（2,4,4-trimethylpentyl） monothiophosphinic acid （Cyanex 302）. The extraction behavior of Cyanex 301/Cyanex 302 and their binary mixtures with HQ towards several lanthanoids （La, Nd, Sm, Tb, Ho, Tm） and yttrium （Y） was investigated. The separation ability of REEs was studied according to the various extraction effects. The extraction mechanisms for yttrium were studied with the methods of slope analysis and constant moles in the synergistic systems. The extracted compounds, the equilibrium constants, and thermodynamic functions were also determined.Synergistic solvent extraction of rare earth elements （REEs） from nitrate medium was investigated with mixtures of 8-hydroxyquinoline （HQ） and acidic organophosphorus extractants, bis（2,4,4-trimethylpentyl） dithiophosphinic acid （Cyanex 301） and bis（2,4,4-trimethylpentyl） monothiophosphinic acid （Cyanex 302）. The extraction behavior of Cyanex 301/Cyanex 302 and their binary mixtures with HQ towards several lanthanoids （La, Nd, Sm, Tb, Ho, Tm） and yttrium （Y） was investigated. The separation ability of REEs was studied according to the various extraction effects. The extraction mechanisms for yttrium were studied with the methods of slope analysis and constant moles in the synergistic systems. The extracted compounds, the equilibrium constants, and thermodynamic functions were also determined.

关 键 词：extraction rare earth elements 8-HYDROXYQUINOLINE Cyanex 301 Cyanex 302 

分 类 号：TQ028.32[化学工程]