A Novel Cadmium(Ⅱ) Complex Based on Asymmetric Dicarboxylate and N-Auxiliary Ligand: Synthesis, Crystal Structure and Properties  

作　　者：王彦 刘志强 王素娜 刘光祥 陈友存 汪潇潇 叶梦 

机构地区：[1]School of Chemistry and Chemical Engineering, Anhui Key Laboratory of Functional Coordination Compounds, Anqing Teachers College [2]State Key Laboratory of Coordination Chemistry, Nanjing University [3]School of Chemistry and Chemical Engineering, Liaocheng University

出　　处：《Chinese Journal of Structural Chemistry》2013年第6期903-907,共5页结构化学（英文）

基　　金：Supported by the National Natural Science Foundation of China (No. 20901004)

摘　　要：One Cd（II） complex based on dicarboxylate and N-auxiliary ligand, namely, [Cd（aip）（m-bix）]n （1, H2aip = 5-aminoisophthalic acid, m-bix = 1,3-bis（imidazol-l-yl-methyl）ben- zene）, was successfully synthesized under hydrothermal conditions. Single-crystal X-ray diffraction analysis reveals that 1 belongs to the orthorhombic system, space group Pbca with a = 14.0790（11）, b = 17.0038（15）, c = 17.3191（16）, V= 4146.1（6） A3, Z = 8, D,. = 1.698 g.cm＂3, p = 1.095 mm-1, F（000） = 2128, the final R = 0.0268 and wR = 0.0623. Complex 1 is a three-dimensional architecture with fsc-3,5-Cmce-1 topology, in which the metal ions act as rare 5-connected nodes. The TGA, XRD and luminescent properties of I were studied.One Cd（II） complex based on dicarboxylate and N-auxiliary ligand, namely, [Cd（aip）（m-bix）]n （1, H2aip = 5-aminoisophthalic acid, m-bix = 1,3-bis（imidazol-l-yl-methyl）ben- zene）, was successfully synthesized under hydrothermal conditions. Single-crystal X-ray diffraction analysis reveals that 1 belongs to the orthorhombic system, space group Pbca with a = 14.0790（11）, b = 17.0038（15）, c = 17.3191（16）, V= 4146.1（6） A3, Z = 8, D,. = 1.698 g.cm＂3, p = 1.095 mm-1, F（000） = 2128, the final R = 0.0268 and wR = 0.0623. Complex 1 is a three-dimensional architecture with fsc-3,5-Cmce-1 topology, in which the metal ions act as rare 5-connected nodes. The TGA, XRD and luminescent properties of I were studied.

关 键 词：crystal engineering TOPOCHEMISTRY hydrothermal synthesis Cd（II） complex 

分 类 号：O627[理学—有机化学]