阴离子型水性聚氨酯的制备及进展  

Research and development of hydrophilic groups of anionic aqueous polyurethane

作　　者：郑英丽[1] 罗洁[1] 宋文生[1] 李平[1] 蔡俊青[1] 

机构地区：[1]河南科技大学化工与制药学院,洛阳471003

出　　处：《化工新型材料》2013年第6期7-8,20,共3页New Chemical Materials

基　　金：河南科技大学人才科学研究基金(05-125);河南科技大学青年基金2009QN0023

摘　　要：综述了阴离子型水性聚氨酯亲水基团的研究状况。亲水基团的引入方式有多种,可以通过小分子扩链剂引入,也可通过含有离子基团的聚酯或聚醚引入,或在水性聚氨酯的分子结构中同时引入磺酸盐和羧酸亲水基团,形成混合内乳化剂,可提高水性聚氨酯的耐水性和其他物理性能,降低溶剂的使用量。Research progress of hydrophilic groups of anionic aqueous p-olyurethane was summarized. There were various ways to incorporate the hy-drophilic groups into polyurethane macromolecules, one of which was using small molec- ular chain extender, and another was using polyester or polyols or both of them. In addition, sulfonate groups and carboxylic acidic groups may also be introduced simultaneously in the molecular structure of pol-yurethane, forming a mixed internal e- mulsifier, which can improve the water-resistance and other physical-chemical properties of WPU and reduced the cont-ent of solvent.

关 键 词：阴离子水性聚氨酯 亲水基团 磺酸盐亲水基团 羧酸亲水基团 

分 类 号：TQ323.8[化学工程—合成树脂塑料工业]