磷酸铝纳米包覆对三元材料性能的影响  

Effect of AlPO_4 nano-coating on electrochemical property of LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2

作　　者：李建军[1] 陈敏[1] 王莉[1] 高剑[1] 何向明[1] 姜长印[1] 

机构地区：[1]清华大学核能与新能源技术研究院,北京100084

出　　处：《化工新型材料》2013年第6期151-153,共3页New Chemical Materials

基　　金：国家973计划(2011CB935902);科技部国际合作(2010DFA72760);清华大学自主科研计划(2010THZ08116;2011THZ08139和2011THZ01004)

摘　　要：为提高三元正极材料的性能,采用纳米AlPO4包覆。并用X射线衍射(XRD),扫描电镜(SEM),透射电镜(TEM)和恒流充放电对包覆和未包覆的材料进行结构表征与性能测试分析。结果表明,AlPO4包覆并没有改变电极材料的晶体结构,仅在电极材料表面形成均匀的包覆层,厚度约为4nm。包覆后的电极材料在3～4.5V的充放电电压范围内,循环性能明显优于未包覆的材料,并且包覆量越高,材料的性能越好。但是包覆量太高会影响其初始容量,研究表明,0.2%的包覆浓度能够提高材料的电化学性能。The performance of LiNi1/3 C01/3 Mn1/3 02 anode material was improved by A1PO4 nano-coating. A1PO4- coated LiNi1/3 Co1/3 Mn1/3 02 was obtained by suspension solution of nano A1PO4. Related characters were investigated by X- ray powder diffraction （XRD）, scanning electron microscope imaging （SEM）, transmission electron microscope imaging （TEM） and charge-discharge cycling test. The results showed that the coating do not change the structure of LiNi1/3 C01/3 Mn1/3 02, its surfaces were covered uniformly by nano A1PO4, and the thickness of coating layer was about 4nm. To enhance the electrochemical performance, A1PO4-coated LiNi1/3 Co1/3 Mn1/3 02 markedly improved capacity retention compared to pristine material upon cycling at 3. 0-4. 5 V. Higher was the weight proportion of coating, better was the performance. However,high weight proportion of coating reduced the capacity. 0. 2wt coating was selected, because it not only im- proved capacity retention upon cycling at 3-4. 5V,but also retained the best capacity of positive material.

关 键 词：锂离子电池 三元材料 AlPO4包覆 纳米 

分 类 号：TM912[电气工程—电力电子与电力传动]