双花千里光中一个新的呋喃骈雅槛蓝烷型倍半萜  

New Furanoeremophilanen Derivative from Senecio dianthus

作　　者：黄帅[1,2] 张吉发[1] 黄晶[1] 周先礼[1] 单连海[1] 王萃娟[1] 翁杰[2] 

机构地区：[1]西南交通大学生命科学与工程学院,成都610031 [2]西南交通大学材料先进技术教育部重点实验室,成都610031

出　　处：《有机化学》2013年第6期1337-1339,共3页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.31171695);四川省科技支撑计划(No.2013SZ0083);中央高校基本科研业务费专项(Nos.SWJTU2010ZT09;SWJTU12CX048)资助项目~~

摘　　要：从藏药双花千里光中分离得到2个倍半萜类化合物,经过HR-ESIMS,1D和2D NMR等光谱技术,将上述化合物鉴定为6-oxo-9α-angloyloxy-10βH-furanoeremophilane(1)和spiroeuryolide(2).化合物1为新的呋喃骈雅槛蓝烷倍半萜.同时,对文献报告中化合物2的13C NMR数据进行了纠正.A new furanoeremophilanen derivative,6-oxo-9a-angloyloxy-10flH-furanoeremophilane （1） was isolated from the aerial parts of Senecio dianthus, together with a known compound, spiroeuryolide 2. Their structures were elucidated on the basis of extensive spectroscopic analysis, including HR-ESI-MS, 1D and 2D NMR experiments. Compound 2 was isolated from the plant for the first time. Complete 1H NMR and 13C NMR spectral assignments of 2 were leading to revision of some 13C NMR assignments previously made for this compound.

关 键 词：菊科 双花千里光 呋喃骈雅槛蓝烷倍半萜 spiroeuryolide 

分 类 号：R284[医药卫生—中药学]