过氧化聚吡咯-铁氰化钴/普鲁士蓝复合膜的制备及应用  

Preparation and Properties of PPyox-Cobalt/Ferric Hexacyanoferrate Film

作　　者：宋诗稳[1,2] 于浩[2] 甄延忠[1] 刘珍叶[2] 齐广才[2] 

机构地区：[1]延安大学能源与环境工程学院,陕西延安716000 [2]延安大学化学与化工学院,陕西延安716000

出　　处：《延安大学学报（自然科学版）》2013年第2期86-89,共4页Journal of Yan'an University：Natural Science Edition

基　　金：延安市科技攻关项目(2012kg-01)

摘　　要：采用循环伏安法在Co2+、Fe3+、K3Fe(CN)6共存的溶液将CoHCF/PB复合膜修饰于过氧化聚吡咯修饰的复合陶瓷碳电极表面(PPyox-CoHCF/PB/CCE)。采用扫描电镜(SEM)方法对修饰电极进行表征,并研究了修饰电极对H2O2的电催化活性。结果表明:PPyox膜的存在更易于Co-HCF/PB在其上的固载、改善了电极表面金属铁氰化物的分散性与修饰电极的电催化活性。在优化的实验条件下,安培法检测H2O2的线性范围为6.0×10-6～4.0×10-3mol.L-1,检出限为3.0×10-6mol.L-1(3 Sb,n=10)。A CoHCF/PB film was electrodeposited on the surface of PPyox/CCE in a solution containing Co^2＋ , Fe^3 ＋ and K3 Fe （CN） 6 using cyclic voltammetry. The morphology of the modified electrode was characterized by scanning electron microscopy （SEM） experiments, and the electrocatalytic performance of the PPyox/CoHCF/PB/CCE modi- fied electrode was investigated. The results showed that the existence of PPyox was favored to the deposition of com- pact and uniform CoHCF/PB film with good adhering. Under the optimum condition, the reduction peak current of the modified electrode was proportional to the concentration of H202 in the range of 6.0 × 10 -6 to 4.0 × 10 -3 mol·L-a with a detection limit of 3.0 × 10-6 mol · L-1 （3 Sb,n = 10）.

关 键 词：铁氰化钴 普鲁士蓝 过氧化聚吡咯 膜修饰电极 电沉积 

分 类 号：O657.1[理学—分析化学]