新型铅(Ⅱ)配合物的水热合成与晶体结构  

Hydrothermal Synthesis and Crystal Structure of a New Lead(Ⅱ) Complex

作　　者：李微微[1] 赵晗[1] 张文通[1] 赵程程[1] 车广波[2] 

机构地区：[1]吉林师范大学化学学院,吉林四平136000 [2]吉林师范大学环境科学与工程学院,吉林四平136000

出　　处：《吉林师范大学学报（自然科学版）》2013年第3期36-39,共4页Journal of Jilin Normal University:Natural Science Edition

基　　金：教育部新世纪优秀人才项目(NCET-10-0176)

摘　　要：利用水热技术,以3,4,5,6-四氟邻苯二甲酸、1,10-邻菲罗啉衍生物、Pb(NO3)2.6H2O为原料合成了铅(Ⅱ)配合物C52H26F8N8O6Pb,并通过元素分析和X射线单晶衍射对其结构进行了表征.该晶体属于单斜晶系,P21/n空间群,a=10.573 5(4),b=16.748 5(5),c=24.649 5(6),β=96.181(3)°,V=4 339.8(2)3,Z=4.结构分析表明该配合物为零维结构,且通过氢键及π-π相互作用使之形成一维链状结构.A new complex C52H26O6N8F8Pb based on 3,4,5,6-Tetrafluoro-phthalic acid,1,10-phenanthroline and its derivatives,Pb（NO3） 2.6H2O has been hydrothermally synthesized and characterized by elemental analysis and single-crystal X-ray diffraction.The title compound crystallizes is in monoclinic space group P21/ n with a = 10.573 5（4）,b = 16.748 5（5）,c = 24.649 5（6）,β = 96.181（3） °,V = 4 339.8（2）3,Z =4.Structure analysis shows that the title compound is zero-dimensional structure,and the neighboring units are further linked into a one-dimensional chain structure by hydrogen bonds and π-π interactions.

关 键 词：铅(Ⅱ)配合物 3 4 5 6-四氟邻苯二甲酸 1 10-邻菲罗啉衍生物 晶体结构 

分 类 号：O611.4[理学—无机化学]