SYNTHESIS, CHARACTERIZATION AND SOME PROPERTIES OF EPOXY RESINS CONTAINING AZOMETHINE BONDING  

作　　者：smet Kaya Murat Gül 

机构地区：[1]anakkale Onsekiz Mart University, Faculty of Sciences and Arts, Department of Chemistry, Polymer Research Laboratory

出　　处：《Chinese Journal of Polymer Science》2013年第8期1087-1095,共9页高分子科学（英文版）

摘　　要：New epoxy resins were prepared from hydroxyl substituted Schiff base monomers in two steps. The first step is based on the synthesis of hydroxyl substituted Schiffbase monomers via condensation reaction. The second step includes the reaction between Schiff base monomers with cpichlorohydrine （EPC） to obtain epoxy resins. The structures of resulting compounds were confirmed by FTIR and H-NMR. TG-DTA and DSC measurements were made for thermal characterizations of the compounds. Chemical resistances of the cured epoxy-amine systems in acidic, alkaline and organic solvents were determined for coating applications. HC1 （aqueous solution, 10%）, NaOH （aqueous solution, 10%）, DMSO, DMF, N-methylpyrrolidone, ethanol, THF and acetone were used for corrosion tests. Chemical resistance data show that the synthesized resins have good chemical resistance against various acid, alkaline and common organic solvents.New epoxy resins were prepared from hydroxyl substituted Schiff base monomers in two steps. The first step is based on the synthesis of hydroxyl substituted Schiffbase monomers via condensation reaction. The second step includes the reaction between Schiff base monomers with cpichlorohydrine （EPC） to obtain epoxy resins. The structures of resulting compounds were confirmed by FTIR and H-NMR. TG-DTA and DSC measurements were made for thermal characterizations of the compounds. Chemical resistances of the cured epoxy-amine systems in acidic, alkaline and organic solvents were determined for coating applications. HC1 （aqueous solution, 10%）, NaOH （aqueous solution, 10%）, DMSO, DMF, N-methylpyrrolidone, ethanol, THF and acetone were used for corrosion tests. Chemical resistance data show that the synthesized resins have good chemical resistance against various acid, alkaline and common organic solvents.

关 键 词：Epoxy resin Thermal analysis Poly（imine）s. 

分 类 号：TQ433.437[化学工程]