电化学基础(Ⅴ)——电极过程动力学及电荷传递过程  

Fundamentals of electrochemistry(Ⅴ)——Electrochemical kinetic and charge-transfer process for electrochemical reaction

作　　者：贾志军[1] 马洪运[1] 吴旭冉[1] 廖斯达[1] 王保国[1] 

机构地区：[1]清华大学化学工程系,北京100084

出　　处：《储能科学与技术》2013年第4期402-409,共8页Energy Storage Science and Technology

基　　金：化学工程联合国家重点实验室2011年自主课题立项;国家自然科学基金项目(21076112;21276134)

摘　　要：电荷传递过程是电化学反应的本质。了解电荷传递过程有助于揭示电化学反应的内在规律,实现电化学工业过程控制和电化学反应设计。本文通过回顾电极过程动力学理论的发展历程及数学表达式的演化过程,阐述电化学反应中电荷传递过程的科学背景,理解其中的科学思想,相信对于促进现代电化学研究的发展具有启示意义。The charge-transfer process is the basis of an electrochemical reaction. The knowledge about charge-transfer processes can help us to recognize to the inherent nature through the electrochemical reaction representation, and to achieve the control in the electrochemical industry and the electrochemical reaction design. In this paper, we reviewed the scientific background of electrochemical kinetic and development of the charge-transfer process, and rethought about their scientific idea. We believe that a historical review can be very heloful for our future research.

关 键 词：电化学 电荷传递 塔菲尔公式 巴特勒-沃尔默公式 量子力学机理 

分 类 号：N092[自然科学总论—科学技术哲学]