关于溶胀法及计算机模拟HNBR三维溶解度参数的研究  

Study on the Three-dimensional Solubility Parameters of HNBR Using Swell Method and Computer Program Simulation

作　　者：刘广永[1] 裘文[1] 商元元[1] 邱桂学[1] Martin Hoch 

机构地区：[1]青岛科技大学橡塑材料与工程教育部重点实验室,山东青岛266042 [2]朗盛化学(中国)有限公司,上海200040

出　　处：《世界橡胶工业》2013年第6期25-30,共6页World Rubber Industry

摘　　要：研究了用溶胀法测定,以及计算机程序(HSPiP)模拟计算氢化丁腈橡胶(HNBR)的三维溶解度参数值,对比了单溶剂溶胀和混合溶剂溶胀HNBR得到的三维溶解度参数值。结果表明,使用溶胀法能够准确地得到HNBR的溶解度参数值。用单溶剂和混合溶剂溶胀HNBR,以及模拟计算得到三维溶解度参数值基本相同,分别为δd=18.4(J/cm3)1/2,δp=6(J/cm3)1/2,δh=4.5(J/cm3)1/2和δd=18.9(J/cm3)1/2,δp=4.8(J/cm3)1/2,δh=5(J/cm3)1/2,而后者具有更明显的优势。相对于一维溶解度参数,聚合物的三维溶解度参数在预测聚合物相容性以及溶剂选择等方面,具有更大的利用价值。The three-dimensional solubility parameters of Hydrogenated nitrile rubber （HNBR） were investigated using swell measurement together with the computer program called HSPiP, and of which the values obtained from various of individual solvents and solvent mixture tests were compared. The results show that the solubility parameters of HNBR can be precisely gained via swell measurement and the three-dimensional solubility parameters gained from individual and mixed solvents are similar as δd - 18.4 （J/cm^3）1/2, δp = 6 （J/cm^3）1/2, δn= 4.5 （J/cm^3）1/2 and δd = 18.9 （J/cm^3）1/2, δp = 4.8 （J/cm^3）t 2 6h = 5 （J/cm^3）1/2 respectively, the latter is better. The three-dimensional solubility parameters of polymer have a larger value in use in prediction for polymer compatibility and solvent selection than the one-dimensional solubility parameters.

关 键 词：氢化丁腈橡胶(HNBR) 溶剂 溶胀法 三维溶解度参数 相容性 

分 类 号：TQ333.7[化学工程—橡胶工业]