Coating of Al_2O_3 on layered Li(Mn_(1/3)Ni_(1/3)Co_(1/3))O_2 using CO_2 as green precipitant and their improved electrochemical performance for lithium ion batteries  

作　　者：Yingqiang Wu Linhai Zhuo Jun Ming Yancun Yu Fengyu Zhao 

机构地区：[1]State Key Laboratory of Electroanalytical Chemistry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences [2]Laboratory of Green Chemistry and Process,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences [3]University of Chinese Academy of Sciences

出　　处：《Journal of Energy Chemistry》2013年第3期468-476,共9页能源化学（英文版）

基　　金：supported by the National Natural Science Foundation of China(21273222)

摘　　要：Li（Mn1/3Ni1/3Co1/3）O2 cathode materials were fabricated by a hydroxide precursor method. A1203 was coated on the surface of the Li（Mn1/3Ni1/3Co1/3）O2 through a simple and effective one-step electrostatic self-assembly method. In the coating process, a NaHCO3- H2CO3 buffer was formed spontaneously when CO2 was introduced into the NaAlO2 solution. Compared with bare Li（Mn1/3Ni1/3Co1/3）O2, the surface-modified samples exhibited better cycling performance, rate capability and rate capability retention. The Al2O3-coated Li（Mn1/3Ni1/3Co1/3）O2 electrodes delivered a discharge capacity of about 115 mAh.g-1 at 2 A.g-1, but only 84 mAh.g-1 for the bare one. The capacity retention of the Al2O3-coated Li（Mn1/3Ni1/3Co1/3）O2 was 90.7% after 50 cycles, about 30% higher than that of the pristine one.Li（Mn1/3Ni1/3Co1/3）O2 cathode materials were fabricated by a hydroxide precursor method. A1203 was coated on the surface of the Li（Mn1/3Ni1/3Co1/3）O2 through a simple and effective one-step electrostatic self-assembly method. In the coating process, a NaHCO3- H2CO3 buffer was formed spontaneously when CO2 was introduced into the NaAlO2 solution. Compared with bare Li（Mn1/3Ni1/3Co1/3）O2, the surface-modified samples exhibited better cycling performance, rate capability and rate capability retention. The Al2O3-coated Li（Mn1/3Ni1/3Co1/3）O2 electrodes delivered a discharge capacity of about 115 mAh.g-1 at 2 A.g-1, but only 84 mAh.g-1 for the bare one. The capacity retention of the Al2O3-coated Li（Mn1/3Ni1/3Co1/3）O2 was 90.7% after 50 cycles, about 30% higher than that of the pristine one.

关 键 词：electrochemistry alumina COATING layered cathode lithium-ion batteries 

分 类 号：TM912[电气工程—电力电子与电力传动] TG174.442[金属学及工艺—金属表面处理]