聚(四甲基对苯二胺)/MoO_3层状材料的制备  

Inclusion of Poly(TMPD) into MoO3 via a Cooperative Formation Route

作　　者：邵柯[1] 马颖[1] 曹亚安[1] 陈朝晖[1] 纪学海[1] 姚建年[1] 

机构地区：[1]中国科学院化学研究所分子科学中心,北京100080

出　　处：《物理化学学报》2000年第10期865-868,共4页Acta Physico-Chimica Sinica

基　　金：国家自然科学基金重点资助!(批准号 :59932040);中国科学院资助项目

摘　　要：Poly(TMPD)/MoO3 was constructed via a cooperative formation route from TMPD and molybdate ammonium at acidified conditions.XRD data showed a layered structure along c axis.IR and Raman spectra confirmed that TMPD had been polymerized and intercalated into MoO3 layers.TGA curve gave the composition of [poly(TMPD)]0.23MoO3(H2O)0.31.Meanwhile,it was found that MoO3 accelerated the polymerization process of TMPD by entrapping the polymer and disturbing the balance between monomer and polymer with deposition of Poly(TMPD)/MoO3.According to this mechanism,a design for constructing layered polymer/MoO3 was proposed and a scheme was drawn also.Poly(TMPD)/MoO3 was constructed via a cooperative formation route from TMPD and molybdate ammonium at acidified conditions.XRD data showed a layered structure along c axis.IR and Raman spectra confirmed that TMPD had been polymerized and intercalated into MoO3 layers.TGA curve gave the composition of [poly(TMPD)]0.23MoO3(H2O)0.31.Meanwhile,it was found that MoO3 accelerated the polymerization process of TMPD by entrapping the polymer and disturbing the balance between monomer and polymer with deposition of Poly(TMPD)/MoO3.According to this mechanism,a design for constructing layered polymer/MoO3 was proposed and a scheme was drawn also.

关 键 词：MOO3 层状结构 聚(四甲基对苯二安) 纳米材料 

分 类 号：O631[理学—高分子化学]