[PMo_9V_3O_(40)]^(6-)硫代物的合成及光谱研究  

Synthesis and Spectroscopic Studies of the Oxothio Heteropolyanio n of [PMo_9V_3O_(40)]^(6-)

作　　者：陈达贵[1] 张汉辉[1] 杨融生[1] 孙瑞卿[1] 杨齐瑜[1] 余秀芬[1] 

机构地区：[1]福州大学化学系,福州350002

出　　处：《光谱学与光谱分析》2000年第5期712-714,共3页Spectroscopy and Spectral Analysis

基　　金：结构化学国家重点实验室(990 0 2 1 )资助

摘　　要：通过H2 S与杂多化合物 (NH4 ) 4H2 [PM9V3 O4 0 ]·10H2 O在DMF中反应合成了其硫代产物 。Some compounds were obtained through addition H 2S to the heteropoly-compound (NH 4) 4H 2[PMo 9V 3O 40]·10H 2 O in dimethyformamide.The FTIR spectrum and NIR FT-Raman spectrum of these comp ounds were investigated.The spectroscopic studies of the compound Ⅱshowed that it is a oxothio heteropoly-compound.

关 键 词：杂多化合物 钒异金属硫桥簇合物 硫化物 光谱 

分 类 号：O614.511[理学—无机化学] O613.51[理学—化学]