十八电子规则适用条件的研究  

STUDY OF SUITABLE CONDITION ABOUT THE EIGHTEEN-ELECTRON RULE

作　　者：吴刚[1] 

机构地区：[1]滁州师范专科学校化学系,安徽滁州239012

出　　处：《安徽师范大学学报（自然科学版）》2000年第3期298-301,共4页Journal of Anhui Normal University(Natural Science)

摘　　要：根据群理论 ,以中心原子和配体的键为基 ,进行对称操作 ,求出可约表示的特征标 ,得出含有π键的八面体配合物遵循十八电子规则 ,无π键的八面体配合物基本遵循十八电子规则 ,无π键的四面体。The article uses goup theory. The bonds of center atom and ligand are regard as base. The base is carried out symmetry operation. The character of reducible representation has been obtained. The results are that octahedral coordination compounds having π bond obey the eighteen-electron rule. The tetrahedral coordination compounds having not π bond and the square coordination compounds having not π bond or having π bond do not obey the eighteen-electron rule.

关 键 词：十八电子规则 配体 八面体配合物 中心原子 

分 类 号：O641.4[理学—物理化学]