磺化琥珀酸酯盐类结合型加脂剂技术发展探讨  

Development of Sulfosuccinate Surfactants Reactive Fatliquor

作　　者：兰云军[1] 毛培[1] 许晓红[1] 罗卫平[1] 

机构地区：[1]温州大学浙江省皮革工程重点实验室,浙江温州325027

出　　处：《中国皮革》2013年第15期36-39,42,共5页China Leather

基　　金：浙江省皮革清洁生产产业技术创新战略联盟支持项目(编号:2012C07)

摘　　要：分析了磺化琥珀酸酯盐类结合型加脂剂近年来的发展进展,并重点探讨了在活性氢类起始原料选择方面的变化及其对产品合成技术和性能的影响,磺化时用亚硫酸钠代替焦亚硫酸钠或亚硫酸氢钠,有助于简化工艺和消除产品中的铵盐组分,同时在磺化时加入水性分散材料,有助于磺化反应的进行和产品稳定性及水乳化分散性的提高。Recent development progress of sulfosucanate surfactants reactive fatliquor were analyzed. The synthetic technique and product performance were influenced by changing different starting materials of activehydrogen. It shows that in the reaction of sulfonation, substituting sodium sulfite for sodium pyrosulfite and sodium bisulfite contribute to simplify process and the removal of ammonium salt from product, the stability of the product and aqueous emulsifying properties are improved by adding aqueous dis- persions materials.

关 键 词：马来酸酐 单酰化 磺化 结合型加脂剂 清洁化 

分 类 号：TQ645.1[化学工程—精细化工]