6-甲氧基-1-萘满酮的合成研究  

Study for the Synthesis of 6-Methoxy-1-Tetralone

作　　者：石剑锋 黄福奎 马世虎[2] 

机构地区：[1]浙江博华环境技术工程有限公司,浙江杭州310012 [2]天津工业大学中空纤维膜材料与膜技术工程教育部实验室,天津300160

出　　处：《浙江化工》2013年第7期17-19,共3页Zhejiang Chemical Industry

摘　　要：以1,6-二羟基萘为起始原料,Raney Ni为催化剂,经催化还原、甲基化合成工艺优化6-甲氧基-1-萘满酮,总收率74%;重点考察了温度,压力,溶剂,氢氧化钠的用量,以及底物浓度对氢化反应的影响,得出了较佳的工艺条件。6-Methoxy-l-tetralone was prepared from 1,6-dihydroxynaphthalene by hydrogenation with Raney Ni and methylation with dimethyl sulfate, and the total yield was above 74%. The effects of pressure, temperature, solvents and the quantity of sodium hydroxide and the concentration of substrate on the yield ofhvdrozenation were screened and obtained the optimized conditions.

关 键 词：1 6-二羟基萘 催化氢化 萘满酮 

分 类 号：TQ463[化学工程—制药化工]