碳纳米管电极电还原降解水中头孢他啶  

Study on Electrochemical Degradation of Ceftazidime by Carbon Nanotubes Electrode

作　　者：朱宏[1] 胡翔[1] 李俊峰[2] 

机构地区：[1]北京化工大学环境科学与工程系,北京100029 [2]中国航天建设集团有限公司,北京100048

出　　处：《环境科学》2013年第8期3125-3131,共7页Environmental Science

基　　金：国家自然科学基金项目(50878014;51178022)

摘　　要：通过SEM、FITR、CV、Tafel等表征,以头孢他啶为目标污染物,研究了自制多壁碳纳米管电极电还原难降解有机物等的特性,并用高效液相色谱检测反应后目标污染物的质量浓度.结果表明,该电极性能稳定,可耐受一定程度的腐蚀,具有较好的性能.循环伏安结果表明,在800 mV左右获得较大的氧化峰,峰值达到-0.2 mA,头孢他啶在该电极上的降解是不可逆的.碳纳米管电极电还原降解头孢他啶的适宜工艺条件为:电极间距1 cm,电压15 V,初始质量浓度1 mg·L-1,离子强度1 g·L-1,pH=6.0.此条件下,反应60 min,头孢他啶的去除效率可达90%以上,该降解过程为二级反应.A self-made multi-walled carbon nanotubes electrode was characterized by SEM,FITR,CV and Tafel,and applied to study the electrochemical reduction degradation of refractory organics,using ceftazidime as model pollutant,and the mass concentration after the reduction was measured by the HPLC.The results indicate that the electrode has perfect stability,good resistance to corrosion,and perfect performance.According to the CV,a larger oxidation peak was obtained at about 800 mV,with a peak value of-0.2 mA,and the degradation of ceftazidime on the electrode was irreversible.The optimum conditions of the the electrochemical reduction degradation of ceftazidime on carbon nanotubes electrode were： electrode spacing of 1 cm,a voltage of 15 V,an initial concentration of 1 mg·L-1,ionic strength of 1 g·L-1,and a pH value of 6.0.Under such conditions,the removal efficiency of ceftazidime reached up to 90% when the reaction time was 60 min,and the degradation process conforms to the second-order kinetics.

关 键 词：碳纳米管电极 电还原 头孢他啶 循环伏安 塔菲尔曲线 

分 类 号：X703.1[环境科学与工程—环境工程]