2-(4-N-硝基,N-甲基氨基苯基)-(4-硝基苯基)-5-(2,4,6,-三硝基苯基)噻唑的合成及其性能研究  

Study on Synthesis and Property of 2 - (4 - N - Nitro - N - Methylaminophenyl) -(4 - Nitrophenyl) - 5 - (2,4,6- Trinitrophenyl) Thiazole

作　　者：赵雷[1] 王世敏[1] 张胜利[1] 常俊丽[1] 陈祖兴[1] 孙俊梅 张干兵[1] 

机构地区：[1]湖北大学化学与材料科学学院,武汉430062

出　　处：《有机化学》2000年第5期750-753,共4页Chinese Journal of Organic Chemistry

基　　金：湖北省教委重点项目(98A005);湖北省自然科学基金(99J075)

摘　　要：为解决非线性光学活性有机分子透明性差及熔点低的问题,设计合成了2-(4-N-硝基,N-甲基氨基苯基)-(4-硝基苯基)-5-(2,4,6-三硝基苯基)噻唑化合物,并研究了其热性能及光学性质。根据实验结果得出由于杂环的引入,提高了化合物的裂解温度,并较好地改善了有机分子的透明性。In order to resolve the problem of poor clarity and low melting temperature of organic nonlinear optical molecules, 2 - (4 - N - nitro - N - methylaminophenyl) - (4 - nitrophenyl) -5- (2,4,6- trinitrophenyl)thiazole was designed and synthesized. The optical and thermal properties of this compound were analyzed. It was found that the decomposition temperature and the clarity were sugnificantly improved.

关 键 词：非线性光学活性 有机分子 噻唑化合物 合成 性能 

分 类 号：O626[理学—有机化学]