六硫基·二(2-甲基吡啶)合锌的结构表征  

Structure Characterization of Zinc Complex with S_6^(2-) and 2-Methylpyridine Ligands

作　　者：陈之荣[1] 李健晖[2] 李鸿钧 

机构地区：[1]福州大学化学系,350002 [2]福建农业大学基础部,350002

出　　处：《Chinese Journal of Structural Chemistry》2000年第5期387-390,共4页结构化学（英文）

摘　　要：标题化合物采用锌粉、硫粉及 2 甲基吡啶直接反应 ,最后得到金黄色晶体 ,其结构由X 射线结晶学分析得到晶体数据。晶体属单斜晶系 ,空间群Cc,Z =4,Mr=,a =7.5 10 (2 ) ,b =17.2 95 (5 ) ,c=13.6 85 (1) ,β =94.6 0 (1)° ,V =1771.7 3,Dc=1.6 6 g/cm3,μ(MoKα) =2 0 .9cm- 1,F(0 0 0 ) =90 4。利用 2 389个独立观察点修正到R =0 .0 5 1,Rw =0 .0 6 1。标题化合物是 1个中性分子 ,分子中有 1个扭曲ZnS2 N2 四面体核心。The title compound has been obtained by reaction of zinc power with sulfur in 2\|methylpyridine. The colour of crystal is gold \|yellow. The structure was determined by X\|ray crystallography.The crystal data for the compound: monoclinic, space group Cc, Z=4, a=7.510(2), b=17.295(5), c=13.685(1), β=94.60(1)°, V=1771.7°\+3, D_c=1.66g/cm\+3, μ(MoKα)=20.9cm\+\{-1\}), F(000)=904. The structure was refined to R=0.051 for 2389 independent observed reflections. In the title compound, the core of ZnS\-2N\-2 shows a distorted tetrahedral geometry.\;

关 键 词：2-甲基吡啶 多硫基 配合物 结构 锌 

分 类 号：O641[理学—物理化学]