1,8-位修饰杂芴类有机光电功能材料的合成与应用  

Synthesis and Applications of 1,8-Functionalized Heterofluorenes for Organic Electronics

作　　者：曹锦珠[1] 王志祥[1] 陈润锋[1,2] 李欢欢[1] 郑超[1] 黄维[2] 

机构地区：[1]南京邮电大学信息材料与纳米技术研究院有机电子与信息显示国家重点实验室培育基地,南京210023 [2]南京工业大学江苏-新加坡有机电子与信息显示联合实验室,南京211816

出　　处：《化学进展》2013年第8期1350-1361,共12页Progress in Chemistry

基　　金：国家重点基础研究发展计划(973)项目(No.2009CB930601);国家自然科学基金项目(No.20804020;21274065);江苏省自然科学基金项目(No.BK2011751);南京邮电大学攀登计划(NY210017)资助

摘　　要：以氧、硫、硅、氮、磷等杂原子取代芴中sp3杂化的碳原子所形成的杂芴,不仅可以通过杂原子和π共轭体系间的相互作用有效地调控材料的电子结构,而且可以影响芴不同位置的修饰,从而得到了广泛关注。本文详细分析了1,8-位修饰杂芴的分子结构特点和光电特性,根据不同的杂原子分类论述了相关材料的合成方法和原理,综述了1,8-位修饰杂芴类材料在磷光主体材料、电致发光材料、太阳能电池材料以及有机配体材料等方面的应用进展,展望了其在有机光电材料方面的应用前景和发展趋势。Heterofluorenes, achieved by substituting the sp3-hybridized carbon of fluorene with oxygen, sulfur, silicon, nitrogen, phosphor etc. , are a series of very interesting optoelectronic materials. They have not only many highly effective ways to modify the electronic structures and properties through the particular interactions between the heteroatom and the conjugated system, but also show different modification properties at different substitution positions due to the influence of the heteroatoms＋ 1,8-Functionalization inspires new properties from widely used materials although the synthesis is always difficuh. Owing to the wide spread progress of heterofluorenes and the 1,8-functionalization strategy, 1,8-functionalized heterofluorenes have received increasing attention in organic optical and electronic materials and devices recently. Herein, we summarized the basic principles of the molecular design, material synthesis, structure-property relations, and optoelectronic device applications of 1,8- functionalized heterofluorenes. The different synthetic methods of various 1,8-functionalized heterofluorenes are reviewed and presented according to different effects of different heteroatoms. Besides, the applications of 1 , 8- functionalized heterofluorenes electroluminescent materials for as host materials for phosphorescent organic light organic light emitting diodes, as photovoltaic materials emitting diodes, as for solar cells, and asfunctional ligands for organic metals are discussed in detail. Finally, the existing key problems and the future development of 1,8-functionalized heterofluorenes are also outlined and suggested.

关 键 词：芴 杂芴 1 8-位修饰 合成 有机光电功能材料 

分 类 号：O625.153[理学—有机化学]