双环戊二烯与环烯烃的共聚反应研究进展  

Research on copolymerization of dicyclopentadiene and cycloolefin

作　　者：郭萌[1] 谢瑛波[1] 张玉清[1] 

机构地区：[1]河南科技大学高分子科学与纳米技术重点实验室,洛阳471003

出　　处：《化工新型材料》2013年第7期16-18,共3页New Chemical Materials

基　　金：河南省杰出人才创新基金项目(074200510019)

摘　　要：聚双环戊二烯(PDCPD)具有优良的力学性能,原料来源易得,用途广泛,但其均聚物的抗冲击性、溶解性等方面有待进一步提高。将双环戊二烯(DCPD)与环烯烃共聚形成新的复合材料能够提高其抗冲强度、耐高温性等,使其具有独特的性能。综述了DCPD与环烯烃共聚合反应的机理,所采用的不同催化体系,以及国内外对DCPD与环烯烃共聚反应的研究概况。Polydicyclopentadine（PDCPD） have excellent mechanical properties and wide uses in various fields, the source of raw material was easy to get. But the impact resistance and solubility of the homopoiymer should be improved fur ther. The copolymerization of dicyclopentadine（IX2PD） and cycloolefin could form a new composite material, which had u nique property to improve its impact resistance, high temperature resistance and so on. The reaction mechanism and the dif- ferent catalysts used by the copolymerization of DCPD and cycloolefin were reviewed, and the research progress of the co- polymerization of DCPD and cycloolefin at home and broad was pointed out.

关 键 词：双环戊二烯 环烯烃 共聚 

分 类 号：O631.5[理学—高分子化学]