微波法制备α-四(4-羧基苯氧基)酞菁锌及其光催化性能  

Microwave assisted synthesis of α-tetra-(p-carboxyphenoxy) phthalocyanine zinc and its photocatalytic properties

作　　者：张魁 毋伟[2] 王倩[2] 陈建峰[2] 祁钦 

机构地区：[1]神华集团北京低碳清洁能源研究所,北京102211 [2]北京化工大学化学工程学院教育部超重力工程研究中心,北京100029

出　　处：《北京化工大学学报（自然科学版）》2013年第4期86-90,共5页Journal of Beijing University of Chemical Technology(Natural Science Edition)

基　　金：国家自然科学基金(21076021)

摘　　要：采用微波辐照法合成了α-四(4-羧基苯氧基)酞菁锌(ZnPc),以UV-Vis,FT-IR等手段对其进行了表征,并以碘量法测定了产物的单线态氧量子产率。结果表明:以2mL N,N二甲基甲酰胺(DMF)为溶剂,0.4mL 1,8-二氮杂二环[5,4,0]十一碳-7-烯(DBU)为催化剂,0.1g 3-(4-羧基苯氧基)邻苯二甲腈及0.03g ZnCl2,800W微波辐照180 s后,可得到产率为75.3%的ZnPc,比传统加热合成产率提高了40.3%。对1,3-二苯基苯并呋喃(DPBF)光漂白实验表明,所合成的ZnPc具有较高的单线态量子产率、光活性和稳定性。By exposure to microwave irradiation, α-tetra-（p-carboxyphenoxy）phthalocyanine zinc （ZnPc） was syn- thesized and the properties of the product were investigated by 1H-NMR, UV-Vis and FT-IR spectroscopy. The io- dide method was used to measure the quantum yields of singlet oxygen formed by the product. ZnPc was prepared in a yield of 75.3% by irradiating a mixture of 2 mL of N, N-dimethylformamide （DMF, as solvent） , 0.4 mL of 1, 8-diazabicyclo [ 5,4,0 ] undec-7-ene （ DBU, as catalyst）, 0. 1 g of 3- （4-carboxyphenoxy） phthalonitrile and 0.03 g of ZnCI2 with a microwave power of 800 W for 180 s. The yield was improved by 40.3% compared with that of the conventional method of synthesis. Chemical quenching tests with 1,3-diphenylisobenzofuran （DPBF） indicated that ZnPc gives high singlet oxygen quantum yields and photo-catalytic ability, and good photo-stability.

关 键 词：微波辐照 酞菁 单线态氧 1 3-二苯基苯并呋喃 

分 类 号：TQ203[化学工程—有机化工]