固体碱KF/Al_2O_3在过渡金属催化的偶联反应中应用研究进展  

Progress of Research on KF/Al_2O_3 Used as a Solid Base in Transition-metal Catalyzed Coupling Reactions

作　　者：唐晓博[1] 张伟[1] 曾纪珺[1] 韩升[1] 吕婧[1] 吕剑[1] 

机构地区：[1]西安近代化学研究所,陕西西安710065

出　　处：《化学世界》2013年第7期435-437,448,共4页Chemical World

摘　　要：自Clark和Ando的等发现KF/Al2O3的特殊性能以来,KF/Al2O3在诸多类型的有机反应中得到应用,并取得了满意的结果。近年来,化学科研工作者不断地对其进行深入的研究,使其在更多有机合成领域得到应用。综述了近年来固体碱KF/Al2O3在过渡金属催化的偶联反应中应用的研究进展。Since the introduction of alumina-supported potassium fluoride（KF） as a solid heterogeneous base by Clark, Ando et al, diverse organic reactions catalysed by it were reported in the literature. Even after decades of its first observationKF/Al2O3 still continues to receive immense limelight. The advances in transition-mettal catalyzed coupling reactions using KF/Al2O3 as solid base were reviewed.

关 键 词：固体碱 KF AL2O3 偶联反应 

分 类 号：TQ426.6[化学工程]