β沸石上 β-甲基萘的催化反应性能研究  

STUDY ON THE CATALYTIC REACTIONS OF β-METHYLNAPHTHALENE (βMN) OVER HβZEOLITES

作　　者：周群[1] 孙芳 裘式纶[2] 蒋大振[2] 庞文琴[2] 

机构地区：[1]苏州大学化学化工学院,苏州215006 [2]吉林大学化学系,长春130023

出　　处：《精细石油化工》2000年第6期42-47,共6页Speciality Petrochemicals

基　　金：江苏省教委自然科学基金资助项目

摘　　要：研究了不同硅铝比 Hβ沸石对β甲基萘的催化性能。结果表明催化活性与β沸石的酸量成顺变关系 ;在硅铝比较高的β沸石上 ,主要发生异构化反应 ,而在硅铝比较低的β沸石上则主要发生歧化反应 ,且歧化反应选择性主要受催化剂的The catalytic reactions of βMN were investigated over Hβzeolite with different SiO 2/Al 2O 3 ratios. It was found that the catalytic activity of the zeolite was related to total amount of acids. The isomerization of βMN mainly occurred on the catalysts with high Si/Al ratios, while disproportionation reaction dominated on the catalysts with low Si/Al ratios. The selectivity of disproportionation reaction strongly depended up on the amount of Lacid sites.

关 键 词：Β-甲基萘 Β沸石 岐化反应 异构化反应 催化 

分 类 号：O625.151[理学—有机化学]