铜基催化剂低温浆态相合成甲醇和甲酸甲酯  

LOW TEMPERATURE SYNTHESIS OF METHANOL AND METHYL FORMATE CATALYZED BY COPPER-BASED CATALYSTS IN A SLURRY REACTOR

作　　者：李顺芬[1] 杨先贵[1] 戴汉松[1] 罗仕忠[1] 贾朝霞[1] 吴玉塘[1] 

机构地区：[1]中科院成都有机化学研究所

出　　处：《石油与天然气化工》2000年第6期287-288,293,共3页Chemical engineering of oil & gas

摘　　要：本文考察了采用三种方法制备的铜基催化剂低温浆态相合成甲醇和甲酸甲酯的活性与选择性。结果表明 ,铜氨络合物溶液沉淀法制备的Cu -Cr催化剂的活性较好 。Low temperature synthesis methanol and methyl formate from syngas in a slurry reactor have been investigated. The results showed that the catalysts prepared by three methods have different activities and selectivities of methanol and methyl formate,and the catalyst prepared by complex precipitation method have higher activity of methanol and methyl formate synthesis.By adding the third metal component,the selectivity of methanol and methyl formate can be increased respectively.

关 键 词：甲醇 甲酸甲酯 铜基催化剂 低温浆态相 合成 

分 类 号：TQ03[化学工程]