Modeling of Ions Mobility in Plasma Like Concept and Transfer Processes in Electrolyte Solutions  

作　　者：Boris Badmaevich Tanganov 

机构地区：[1]East Siberia State University of Technology and Management, Ulan- Ude 670013, Russia

出　　处：《Journal of Chemistry and Chemical Engineering》2013年第8期711-724,共14页化学与化工（英文版）

摘　　要：Plasma like concept of ions in electrolyte solutions is accepted as a basis for development of equation mobility for transfer processes （viscosity, diffusion, thermal conductivity and electrical conductivity）. The examples of isomorphism of dissipative processes are given in the article. The integrated assessment equation of transfer properties is developed based on the ion-dipole, dipole-dipole and ion-ion interactions and the force of liquid dielectric resistance to oscillating solvated particles. It is shown that the estimated magnitude of viscosity, diffusion, electrical conductivity and thermal conductivity are comparable with the current knowledge and experimental values in a wide range of electrolyte concentrations.

关 键 词：Plasma like concept solvation intermolecular interactions the mobility of the ions viscosity diffusion ELECTRICALCONDUCTIVITY thermal conductivity. 

分 类 号：O646.1[理学—物理化学] TG174.442[理学—化学]