小型流化床实验台上镍基载氧体的积炭特性  

Investigation on the carbon deposition of Ni-based oxygen carriers in a small-scale fluidized bed

作　　者：张号[1] 金晶[1] 刘帅[2] 路遥[1] 张传美[1] 蒋杰[1] 

机构地区：[1]上海理工大学能源与动力工程学院,上海200093 [2]中国船舶重工集团公司第七一一研究所,上海201100

出　　处：《化工进展》2013年第1期104-107,113,共5页Chemical Industry and Engineering Progress

基　　金：上海市教委科研创新项目(12ZZ141)

摘　　要：采用小型流化床反应器,研究了Ni基载氧体在不同还原气氛(CH4、CO+H2)和不同反应温度(650℃、750℃、850℃、950℃)下的反应特性。结果表明:Ni基载氧体在两种气氛下均表现出较高的反应活性,CO+H2气氛下的还原反应比CH4气氛下的还原反应更完全,两个还原过程中均有积炭的产生,CH4气氛下的积炭比CO+H2气氛下的积炭更为严重;在CH4气氛下,温度的升高有利于Ni基载氧体还原反应的进行,同时还原过程中产生的积炭量也随着温度的升高有所增加,但当温度升高到850℃后,温度的增加对还原反应的影响不大。另外,相比于Cu基载氧体,Ni基载氧体虽然有更好的反应活性,但在还原过程中更容易产生积炭。A small-scale fluidized bed was used to study the reactivity of Ni-based oxygen carriers under the reducing conditions（CH4and CO＋H2） at different reaction temperatures（650 ℃,750 ℃,850 ℃,950 ℃）.The results reveal that nickel-based oxygen carriers have a high reactivity in both CH4and CO＋H2atmospheres,and the reaction is more complete under the atmosphere of CO＋H2.Furthermore,carbon deposition is found in both reduction processes,but it is more serious in CH4 atmosphere.In addition,the increase of temperature has a great influence on the reactivity of nickel-based oxygen carriers as well as the degree of carbon deposition,but it has less effect on the reduction reaction when the temperature exceeds 850 ℃.Also,nickel-based oxygen carriers have a better reactivity compared with copper-based oxygen carriers,but it is easier to produce carbon deposition during the reduction process.

关 键 词：小型流化床 Ni基载氧体 积炭特性 

分 类 号：TK16[动力工程及工程热物理—热能工程] TQ511.1[化学工程]