石墨相氮化碳的化学合成及应用  

Chemical Synthesis and Applications of Graphitic Carbon Nitride

作　　者：张金水[1] 王博[1] 王心晨[1] 

机构地区：[1]福州大学化学化工学院,光催化研究所,福州350002

出　　处：《物理化学学报》2013年第9期1865-1876,共12页Acta Physico-Chimica Sinica

基　　金：国家重点基础研究发展规划(973)(2013CB632405);国家自然科学基金(21033003;21173043;J1103303)资助项目~~

摘　　要：石墨相氮化碳(g-C_3N_4)具有独特的电子结构和优异的化学稳定性,近年来不仅被作为不含金属组分的催化剂和催化剂载体,广泛地应用于有机官能团的选择性转换、光催化分解水、氧还原和Au、Pd、Ag、Pt等贵金属的负载,还被作为绿色储能材料和硬模板剂用于H_2、CO_2的存储和纳米金属氮(氧)化物的制备等,在能源和材料相关领域逐渐引起人们的关注.本文将从材料的制备和应用角度,综述国内外同行近年来在g-C_3N_4研究中所取得的一些重要进展,并对其未来发展趋势,特别是在能源和环境领域中的应用进行了展望.Recently, polymeric semiconductor graphitic carbon nitride （g-C3N4） has been widely used in fields related to energy and material science, because of its unique electronic structure and excellent chemical inertness. For example, it can function as a metal-free catalyst or as a catalyst support for organic synthesis, photocatalytic water splitting, oxygen reduction reactions, and loading of Au, Pd, Ag, and Pt nanoparticles. In addition, it can also serve as a porous covalent organic framework for the absorption of H2 and CO2 gases, or as a hard template for the generation of metal （oxy）nitrides. In this review, some recent advances in g-C3N4 synthesis and applications are presented. The prospects for the development of g-C3N4 in energy-and environment-related fields are also discussed.

关 键 词：石墨相氮化碳 聚合物半导体 材料制备 应用研究 

分 类 号：O643.36[理学—物理化学]