化学沉积法改善纤维-水泥基体的界面性能  

Improvement of the Interfacial Properties of Fiber-Cement Matrix by Chemical Deposition

作　　者：阳知乾[1] 刘建忠[1] 刘加平[1] 李长风[1] 周华新[1] 

机构地区：[1]江苏省建筑科学研究院有限公司高性能土木工程材料国家重点实验室,江苏南京210008

出　　处：《建筑材料学报》2013年第4期699-705,共7页Journal of Building Materials

基　　金：国家重点基础研究发展计划(973计划)项目(2010CB735801);国家自然科学基金资助项目(50908104);江苏省自然科学基金资助项目(BK2011835)

摘　　要：为了改善合成纤维-水泥基体界面黏结性质,通过化学沉积纳米二氧化硅,制备了一系列的改性纤维.使用X射线能谱仪(EDS)确认二氧化硅的存在,采用扫描电镜(SEM)观察纳米颗粒在纤维表面的分布,从而评价化学沉积时间对沉积效果的影响,并通过单丝纤维拔出行为和塑性抗裂性能试验证实改性纤维的优势.结果表明:对聚丙烯(PP)纤维而言,合适的化学沉积时间为60min,此时纳米二氧化硅粒子的平均粒径为300nm;聚乙烯醇(PVA)纤维表面具有的亲水性质,使纳米二氧化硅在其上的分布形态与在PP纤维上明显不同;改性纤维的界面黏结强度显著提高,表现出优良的抗裂性能,其原因可能是由于二氧化硅的水化活性,水化产物在单丝拔出及塑性抗裂时起到了物理锚固及化学键合的双重作用.In order to improve the interracial bonding properties of synthetic fiber-cement matrix, a series of modified fibers were prepared by sol-gel chemical deposition of nano-silica. The effect of chemical depo- sition time on modification efficiency and the distribution of nano-particles on the fiber surface were ob- served with energy dispersive spectrometer（EDS） and scanning electron microscope（SEM）. Single fiber pull-out behavior and plastic crack-resistance experiments were carried out to confirm the advantage of modified fiber. The results demonstrate that the proper chemical deposition time is 60 min for polypropyl- ene（PP） fiber and the mean diameter of nano-silica particles is about 300 nm. As for hydrophilic property, the distribution morphology of nano-silica on polyvinyl alcohol（PVA） fiber surface is obviously different. The interracial bond strength of modified fiber-matrix is improved significantly from the pull-out behavior curves, therefore, all the modified fibers have excellent crack-resistance property. The interracial property of fiber-matrix is improved because of hydration activity of silica. The htgdration products act as chemical combination and physical anchors during pull-out and crack-resistance.

关 键 词：改性纤维 二氧化硅 溶胶-凝胶化学沉积 界面黏结 拔出 抗裂 

分 类 号：TU528.572[建筑科学—建筑技术科学]