2-(4,5-二苯基-1H-咪唑)-4-噻吩Cu(I)配合物的合成及晶体结构  

Synthesis and Crystal Structure of 2-(4,5-diphenyl-1H-imidazole)-4-thiophene Cu(I) Compound

作　　者：刘盼[1] 寇姗姗[1] 崔雯[1] 徐丽[1] 颜秋竹[1] 唐果东[1,2] 

机构地区：[1]淮阴师范学院化学化工学院,江苏淮安223300 [2]南京理工大学化工学院,江苏南京210094

出　　处：《淮阴师范学院学报（自然科学版）》2013年第2期140-143,共4页Journal of Huaiyin Teachers College;Natural Science Edition

基　　金：江苏省高校博士后基金资助项目(1001010C);江苏省高校大学生实践创新训练计划项目

摘　　要：采用2-(4,5-二苯基-1H-咪唑)-4-噻吩配体,合成了该配体的铜(I)的配合物.采用X-射线单晶衍射仪测定了晶体的结构,结果显示,该配合物属单斜晶系,C2/c空间群,晶胞参数为:a=23·476(5)°A,b=11·393(2)°A,c=23·508(5)°A,β=91·55(°),R1=0·0717,wR2=0·2365.研究了该配合物的吸收光谱、发射光谱和电化学性质.2-（4, 5-diphenyl-lH-imidazole）-4-thiophene Cu（I） compound had been synthesized by using benzyl as the star material, the structural of the compound was determined by the single-crystal X-my diffraction, the result shows that the compound has monoclinic system, space group： C2/c, cell parameters： a = 23.476（5） A, b = 11.393（2） A, c = 23.508（5） A, β = 91.55 （°）, R1 = 0.0717, wR2 = 0.2365. The absorption spectrum, emission spectrum and the electrochemistry were studied, too.

关 键 词：2-(4 5-二苯基-1H-咪唑)-4-噻吩Cu(Ⅰ) 晶体结构 光谱性质 

分 类 号：O641.4[理学—物理化学]