相反电荷聚电解质／表面活性剂体系界面行为研究新进展  

New Progress in Interfacial Behavior of Oppositely Charged Polyelectrolyte/Surfactant Systems

作　　者：潘虹[1] 石军[1] 赵康[2] 程发[3] 

机构地区：[1]天津农学院基础科学系,天津300384 [2]天津市奶牛发展中心,天津300384 [3]天津大学理学院化学系,天津300072

出　　处：《高分子通报》2013年第8期13-21,共9页Polymer Bulletin

基　　金：国家自然科学基金基金(21274106)

摘　　要：介绍了中子反射在相反电荷聚电解质/表面活性剂体系的界面行为研究中的基本原理。在阐述经典的弱相互作用体系的界面吸附行为和表面张力曲线的基础上,分析了聚合物浓度、电解质、表面活性剂疏水基链长对相反电荷聚电解质/表面活性剂体系表面张力曲线的影响,并结合中子反射实验结果,根据相反电荷聚电解质/表面活性剂体系的表面张力曲线是否出现突跃峰,将其界面吸附行为分为两类并提出了两种类型表面张力曲线对应的理论模型。In this paper, basic principle of neutron reflectivity techniques, used in the oppositely charged polyelectrolyte/suffactant systems, was introduced. On the basis of introduction of the interracial behavior and the surface tension curve of the weak interaction system, the effect of the polymer concentration, electrolyte and the chain length of surfactant on the surface tension were analyzed. According to the data determined by the neutron reflectivity and the existence of the surface tension peak, the interracial behavior, the types of surface tension plots and theoretical model for oppositely charged polyelectrolyte/surfactant systems were pointed out.

关 键 词：相反电荷聚电解质 表面活性剂 中子反射 表面张力 

分 类 号：O647.2[理学—物理化学]