双水杨醛缩邻苯二胺钙配合物与DNA相互作用的光谱性质  

Spectral Property of Bis-salicylaldehyde O-phenylenediamine Calcium Complex Interact with DNA

作　　者：韩向斌[1] 张连阳 刘西豪[1] 刘慧敏[1] 邵颖[1] 

机构地区：[1]绍兴文理学院化学化工学院,浙江绍兴312000

出　　处：《广东化工》2013年第18期37-38,57,共3页Guangdong Chemical Industry

摘　　要：合成了新的双水杨醛缩邻苯二胺钙配合物,并通过红外光谱、核磁共振谱法对其结构进行表征,并利用紫外光谱和荧光光谱法研究了钙配合物与DNA的相互作用方式,实验研究表明配合物与DNA之间很可能是嵌入作用和部分嵌入作用并存。A new complex Bis-salicylaldehyde o-phenylenediamine Calcium（Ⅱ） was synthesized and characterized by IR and I H NMR. The interaction of the complex with DNA was studied by UV spectrum and fluorescence spectrum. The results indicated that the complex could interact with DNA by the role of embedded and partly embedded with DNA.

关 键 词：DNA相互作用 Ca配合物 光谱 

分 类 号：TQ[化学工程]