氢化诺卜基甲酸及其酯类化合物的质谱解析  

Mass Spectrometric Analysis of Hydronopylformic Acid and Its Esters

作　　者：肖转泉[1] 刘艳[2] 陈金珠[3] 王宗德[2] 

机构地区：[1]江西师范大学化学化工学院,江西南昌330027 [2]江西农业大学林学院,江西南昌330045 [3]江西农业大学理学院,江西南昌330045

出　　处：《江西师范大学学报（自然科学版）》2013年第4期345-348,共4页Journal of Jiangxi Normal University(Natural Science Edition)

基　　金：国家自然科学基金(31060101);国家林业公益性行业科研专项经费课题(201304602);广西民族大学林产化学与工程重点实验室基金(GXFC11-07)资助项目

摘　　要：对由氢化诺卜基氯与镁反应,再和二氧化碳反应合成的氢化诺卜基甲酸及其6个烷基酯进行了质谱分析.通过对质谱数据的解析,获得了在70 eV下这些化合物的质谱裂解情况.Mass spectrometric data of hydronopylformic acid and its six ether derivatives were analyzed.Hydronopylformic acid was synthesized from the reaction of CO 2 and hydronopyl magnesium chloride which was prepared through the Grignard reaction of hydronopyl chloride and magnesium.Mass cleavage characteristics of these compounds under 70 eV was discussed according to the MS spectrometric data.

关 键 词：氢化诺卜基甲酸 酯类 质谱分析 质谱裂解 

分 类 号：O657.63[理学—分析化学]