物理吸附储氢材料的研究进展  

Study Progress on the Hydrogen Storage Material by Physical Absorption

作　　者：张峰[1] 冯翠红 张丽鹏[1] 于先进[1] 

机构地区：[1]山东理工大学化学工程学院,淄博255049 [2]山东大成农化有限公司,淄博255009

出　　处：《硅酸盐通报》2013年第9期1785-1789,1793,共6页Bulletin of the Chinese Ceramic Society

基　　金：国家自然科学基金资助项目(51054003;50374045);山东省自然科学基金资助项目(Y2007F60);山东省高等学校科技计划资助项目(J09LB59);山东省中青年科学家科研奖励基金资助项目(BS2009NJ007)

摘　　要：本文对物理吸附材料主要包括碳基储氢材料及其衍生物、沸石(分子筛)、金属有机物骨架、共价有机物骨架等进行了综述,这类材料具有高比表面积、低温储氢性能好等特点;但常温或高温储氢性能差的特点也制约了物理吸附的发展。本文最后对新型储氢材料研究进行了展望,重点在于高可逆性、高容量、高效催化加氢、常温常压下储存与运输、温和条件下可控催化脱氢等性能的研究。This paper made a general review about physical absorption material including carbon hydrogen storage material and derivatives, zeolites, metal-organic frameworks （ MOFs ）, covalent organic frameworks （COFs） etc. They have the characteristics of high specific surface area, the well hydrogen storage property at normal temperature etc. But the poor hydrogen storage properties when it~ normal temperature or high temperature restrict the development of physical absorption. This paper prospects the research of New type of hydrogen storage material and focus on the study of the characteristics including high reversibility, high capacity, efficient hydrogenation at a large scale, storage and delivery under near ambient conditions and controllable dehydrogenation under mild conditions.

关 键 词：氢能 物理吸附材料 展望 

分 类 号：TB332[一般工业技术—材料科学与工程]