微波辅助合成芳烃钌(Ⅱ)配合物[(η~6-RC_6H_5)Ru(m-MOPIP)Cl]Cl  

Microwave-Assisted Synthesis of Arene Ru(Ⅱ) Complexes[(η~6-RC_6H_5)Ru(m-MOPIP)Cl]Cl

作　　者：吴琼[1] 吴剑[1] 梅文杰[1] 姚骏骅[2] 吴韦黎[1] 陈燕华[1] 陶韵伊[1] 

机构地区：[1]广东药学院药科学院,广州510006 [2]中山大学测试中心,广州510275

出　　处：《有机化学》2013年第9期2022-2027,共6页Chinese Journal of Organic Chemistry

基　　金：广东省科技计划(No.2013J4100072);广州市科技计划(No.7411791521750)资助项目~~

摘　　要：运用微波辅助合成技术,在二氯甲烷溶液中,60℃条件下,Pyrex管中微波辐射30 min制备得到芳烃钌(Ⅱ)化合物[(η6-RC6H5)Ru(m-MOPIP)Cl]Cl(R=H 3a,R=CH33b;m-MOPIP=2-(3-甲氧苯基)-咪唑并[4,5f][1,10]菲啰啉),反应产率分别为90%和91%,目标化合物运用1H NMR,13C NMR,IR,ESI-MS以及1H-1H COSY进行表征;在相同条件下SiC管中,屏蔽微波辐射对反应的影响,3a和3b的产率分别为89%和90%,说明微波"非热效应"对芳烃钌(Ⅱ)配合物的合成没有显著影响.Two arene Ru（II） complexes[（η6-RC6H5）Ru（m-MOPIP）Cl]＋ （R=H 3a, R=CH3 3b; m-MOPIP=2-（3-meth- oxyphenyl）imidazole[4,5-f][1,10]phenanthroline） were prepared under the microwave irradiation at 60 ℃ for 30 min in Pyrex vessel with the yield of about 90% and 91%, and the target compounds were characterized by 1H NMR, 13C NMR, IR, ESI-MS and 1H-1H COSY spectra. At the same reaction conditions, application of SiC vessel to screen the effect of microwave irradiation, 3a and 3b were obtained with the yield of about 89% and 90%. These results indicated that the microwave ＂non-thermal effect＂ has no obvious influence on the synthesis of arene Ru（II） complexes.

关 键 词：微波辅助合成 2-(3-甲氧基苯基)-咪唑并[4 5f][1 10]菲啰啉 芳烃钌(Ⅱ)配合物 

分 类 号：O627[理学—有机化学]