过渡金属催化脱羧反应研究进展  

Research Progress in Transition Metal-catalyzed Decarboxylation Reaction

作　　者：米艳华[1] 

机构地区：[1]温州大学化学与材料工程学院,浙江温州325035

出　　处：《辽宁化工》2013年第9期1081-1082,1159,共3页Liaoning Chemical Industry

摘　　要：羧基是有机化合物常见的官能团,对于羧酸类化合物,一般都需要在很高的温度下才可以使它们脱去CO2分子,随着过渡金属催化的偶联反应的发展,从而相应的过渡金属催化的脱羧反应也得到了发展,文章中我们将对各种过渡金属(如Pd、Cu、Rh等)催化下的脱酸反应进行介绍。The carboxyl group is a common functional group of organic compounds. Aryl carboxylic acids generally require high temperature to remove CO2 from their carboxyl.Along with the development of transition metal catalyzed coupling reaction, the transition metal-catalyzed decarboxylation reaction has also been developed.In this paper, a variety of transition metals （such as Pd, Cu, Rh, etc.） catalyzed deacidification reactions were introduced.

关 键 词：过渡金属 脱羧 偶联反应 

分 类 号：TQ032[化学工程]