稀土水杨酸邻菲罗啉三元固体配合物的研究  

Study on the Complexes of Rare Earth with Salicylic Acid and 1,10-Phenanthroline

作　　者：王则民[1] 何其庄[1] 俞膺浩[1] 罗衍庆[1] 曹锦荣 

机构地区：[1]上海师范大学生命与环境科学学院,上海200234

出　　处：《上海师范大学学报（自然科学版）》2000年第1期70-74,共5页Journal of Shanghai Normal University(Natural Sciences)

摘　　要：合成了 4种稀土水杨酸邻菲罗啉三元固体配合物 ,其通式为RE(Hsal) 3phen(RE =La ,Nd ,Eu ,Er;Hsal=水杨酸根 ;phen =邻菲罗啉 )。通过元素分析 ,摩尔电导 ,IR ,UV ,XPS和TG DTA分析 ,研究了配合物的组成和性质。Four new ternary solid complexes of rare earth (RE) with salicylic acid (H 2sal) and 1,10 phenanthroline (phen) were synthesized. The general formula of these complexes can be expressed as RE(Hsal) 3·phen (RE = La,Nd,Eu,Er). Their composition and properties were investigated by elemental analysis, molar conductance, IR spectra, UV spectra, XPS and TG DTA analysis.

关 键 词：水杨酸 邻菲罗啉 三元固体配合物 稀土配合物 

分 类 号：O614.33[理学—无机化学]