固溶体Fe_(2-x)Yb_xMo_3O_(12)的相变、吸水性及热膨胀性能  

Phase Transition,Hygroscopicity and Thermal Expansion of Fe_(2-x)Yb_xMo_3O_(12) Solid Solutions

作　　者：王燕燕[1] 刘献省[1] 朱志鲜[1] 宋文博[1] 袁保合[1] 梁二军[1] 

机构地区：[1]郑州大学物理工程学院教育部材料物理重点实验室,郑州450052

出　　处：《光散射学报》2013年第3期258-263,共6页The Journal of Light Scattering

基　　金：国家自然科学基金(10974183;11104252);郑州市创新团队(2011-3)

摘　　要：采用固相烧结法,以Yb2O3、MoO3、Fe3O4为原料制备了Fe2-x Ybx Mo3O12(x=0,0.2,0.4,0.6,0.8,1,1.2,1.4,1.6,1.8,2)系列固溶体,并通过X射线衍射图样、Raman光谱、热分析以及膨胀系数测试对其结构、相变、吸水性及热膨胀性能进行了研究。结果表明Fe2-x Ybx Mo3O12当x≤0.4时是单斜相,当x≥0.6时是正交相,随着x值的增加Fe2-x Ybx Mo3O12材料的相变温度逐渐降低。Fe2-x Ybx Mo3O12含有的水分子可以分为两类,一类吸附在晶体表面对晶格振动没有影响,第二类进入晶体内部对晶格振动产生较大影响,导致负膨胀性质的消失,只有完全失去水分子后才表现负热膨胀性能。Fe2-xYbxMo3O12（x=0,0.2,0.4,0.6,0.8,1,1.2,1.4,1.6,1.8,2） are synthesized with solid state method,and characterized for crystal structure,hygroscopicity and thermal expansion by X-ray diffraction,Raman spectroscopy,thermal analysis and dilatometer.The investigation shows that Fe2-xYbx Mo3O12 present monoclinic phase for x ≤0.4 and orthorhombic phase for x≥0.6.The phase transition temperature of Fe2-xYbx Mo3O12 decreases with increasing the x value.Fe2-xYbxMo3O12 possess two kinds of water molecule：one distributing on the surface of crystal has less effect on crystal vibrations;another entering inside of crystal has significant effect on lattice vibrations.The negative thermal expansion property can present only after complete release of the crystal water.

关 键 词：固溶体 相变 吸水性 热膨胀 

分 类 号：O469[理学—凝聚态物理] TB39[理学—电子物理学]