表面流人工湿地中硫丹的去除规律研究  

Study on Removal Rule of Endosulfan in Surface Flow Constructed Wetland

作　　者：秦晶[1] 高甫威[2] 谢慧君[1] 

机构地区：[1]山东大学环境研究院,济南250199 [2]山东省环境保护科学研究设计院,济南250013

出　　处：《环境科学》2013年第11期4251-4256,共6页Environmental Science

基　　金：国家自然科学基金项目(21007032)

摘　　要：硫丹是一种环境中广泛存在的有机氯类污染物,本研究探讨了3个不同浓度梯度的硫丹在表面流人工湿地各组成成分中的去除规律.利用索氏提取-气相色谱法分别测定水、植物、非根际基质以及根际基质中硫丹的含量.结果表明,人工湿地在去除硫丹方面具有很大的优势,30 d内硫丹在人工湿地的水、非根际基质、根际基质中的平均去除率分别为87.9%、63.0%、70.9%.在该系统中,α-硫丹比β-硫丹更加容易去除,主要累积的降解产物为硫丹硫酸酯.基质吸附对人工湿地去除硫丹有很大作用,3 d内,水中约80.0%的硫丹被吸附到基质中.植物对硫丹的去除有很大的促进作用,由于植物的影响,根际基质对硫丹的平均去除率比非根际基质高7.9%.Endosulfan is a kind of widespread organochlorine pollutant in the environment. The removal rule of three different concentrations of endosulfan in different parts of a surface flow constructed wetland was investigated. The concentrations of endosulfan in water, plants, non-rhizosphere sediments and rhizosphere sediments were determined by the Soxhlet extraction-GC method. The results showed that constructed wetland was efficient in endosulfan removal. The removal rate of endousulfan in water, non-rhizosphere sediments and rhizosphere sediments was 87.9% , 63.0% and 70. 9% , respectively. In this system, α-endosulfan was removed faster than β-endosulfan and the metabolite accumulated was mainly endosulfan sulfate. The adsorption of sediments played an important role in the removal of endosulfan. About 80. 0% of endosulfan in water could be adsorbed by sediments within three days. The removal rate of endosulfan could be enhanced by plants. Because of the effect of plants, the average removal rate of endosulfan in rhizosphere sediments was 7.9% higher than that in non-rhizosphere sediments.

关 键 词：表面流人工湿地 硫丹 去除 降解动力学 植物 

分 类 号：X52[环境科学与工程—环境工程]