膜吸收器碳酸钠溶液脱除天然气中硫化氢的研究  

Study on removal of hydrogen sulfide from natural gas by a membrane contactor with sodium carbonate solution as absorbent

作　　者：马路[1] 王树立[1] 王剑[1] 王恒[1] 何双双[1] 刘永亮[1] 

机构地区：[1]常州大学江苏省油气储运技术重点实验室,江苏常州213016

出　　处：《天然气化工—C1化学与化工》2013年第5期51-54,共4页Natural Gas Chemical Industry

基　　金：江苏省科技厅资助项目(BY2011127);(BY2012095);中石油科技创新基金项目(2012D-5006-0604)

摘　　要：以疏水性聚偏氟乙烯中空纤维膜组件为吸收器,碳酸钠水溶液为吸收液,研究了膜孔径和操作条件对天然气脱除硫化氢效果的影响。结果表明:随着气液流量、吸收液浓度和温度的提高,总传质系数也随之提高;膜孔径对传质系数有较大影响,孔径越大传质系数越高;进气流量对总传质系数的影响最大,液体流量的影响最小。The effects of membrane pore-diameter and operation conditions on the removal of hydrogen sulfide from natural gas by the hydrophobic hollow fiber membrane contactor using sodium carbonate solution as absorbent were investigated. The results showed that the mass transfer coefficient increased with the increase of the velocities of feed gas and liquid and the temperature and concentration of absorbent; the pore-diameters had a significant influence on the mass transfer coefficient, the larger the pore- diameter the higher the mass transfer coelficient; and the velocity of feed gas was the most important factor which influenced the overall mass transfer coefficient, but the influence of the velocity of liquid could be ignored.

关 键 词：硫化氢 膜吸收 碳酸钠水溶液 总传质系数 

分 类 号：TQ028.2[化学工程] TE64[石油与天然气工程—油气加工工程]