一些双二茂铁基烷的合成与表征  

Synthesis and Characterization of Some Bis-ferrocenylalkanes

作　　者：温国华[1] 旭昀[1] 罗美华[1] 盛显良[1] 

机构地区：[1]内蒙古大学化学化工学院,内蒙古呼和浩特010021

出　　处：《内蒙古大学学报（自然科学版）》2000年第6期600-604,共5页Journal of Inner Mongolia University：Natural Science Edition

摘　　要：采用浓流酸—甲醇为催化剂 ,以甲苯为溶剂进行二茂铁与一些甲基酮的缩合反应 ,经真空升华除去未反应的二茂铁 ,层析分离分别得到了两种 1 -取代苯基 -1 -二茂铁基乙烯 ,以及六种双二茂铁基烷 .通过元素分析、红外光谱。Ferrocene was condensed with ketone in toluene with the mixture of methanol and concentrated sulfuric acid as catalyst, the unreacted ferrocene was removed by vacuum sublimation, two 1 ferrocenyl olfines and six bis ferrcoenyl alkanes were obtained by chromatography. The structures of these compounds were characterized by elemental analyses, IR and ′HNMR spectra.

关 键 词：缩合 双二茂铁基烷 1-二茂铁基烯 

分 类 号：O627.81[理学—有机化学]