GC-MS法测定电子电气塑料产品中的磷酸三(2-氯乙基)酯  

Determination of Tris(2-chloroethyl phosphate) in Plastic Parts of Electrical and Electronic Products by Gas Chromatography-Mass Spectrometry

作　　者：陈梅[1,2] 蒋小良[3] 

机构地区：[1]中山大学物理科学和工程技术学院,广东广州510275 [2]东风日产乘用车公司,广东广州510800 [3]江门出入境检验检疫局,广东江门529000

出　　处：《塑料科技》2013年第11期85-89,共5页Plastics Science and Technology

摘　　要：建立了气相色谱-质谱（GC—MS）法测定电子电气塑料产品中的有机磷酸酯阻燃剂—磷酸-（2-氟乙基）醢含量的分析检潮方法。样品经微波萃取后，过固相硅胶净化小柱净化，然后用气相色谱．质谱仪进行选择离子监测模式下的定性及定量分析。结果表明：该方法的检出限为0．05mg／kg，样品加标回收率为87．5％-92．9％。相对标准偏差小于4。1％。该方法适用于电子电气塑料产品中有机磷阻燃剂磷酸-（2-氯乙基）酯含量的快速测定，具有操作简单．方便．炙敏度高．结果稳定薄优点。An effective method was established for the determination of the content of organophosphorous flame retardants tris（2-chloroethyl phosphate） （TCEP） in plastic parts of electrical and electronic products by gas chromatography-mass spectrometry（GC-MS）. Sample was treated with microwave extraction, and a solid-phase silicone column was used for the purification. Then qualitative and quantitative analysis was conducted under selected ion monitoring （SIM） mode by GC-MS. The results show that the detection limit is as low as 0.05 mg/kg, the recovery varies from 87.5% to 92.9%, and with relative standard deviation （RSD） is below 4.1%. It is demonstrated that the organophosphorous flame retardants can be analyzed simply by this method and the results are sensitive, accurate and stable.

关 键 词：微波萃取 磷酸三(2-氯乙基)酯 电子电气产品 塑料 气相色谱-质谱法 

分 类 号：TQ320.77[化学工程—合成树脂塑料工业]