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作 者:李霄[1,2] 都基众[2] 张哲[2] 王晓光[2] 崔健[2] 柴璐[2]
机构地区:[1]吉林大学环境与资源学院,吉林长春130026 [2]沈阳地质矿产研究所,辽宁沈阳110034
出 处:《环境科学研究》2013年第11期1162-1170,共9页Research of Environmental Sciences
基 金:国家地质大调查项目(1212010913004)
摘 要:为研究有机组分在地下水中的运移规律及影响因素,并预测水质的破坏程度,利用数值模拟方法建立浑河中游区域特征有机污染组分1,2-DCA(1,2-二氯乙烷)的溶质运移模型,分析1,2-DCA在浑河中游地下水中的运移规律,并预测了其对地下水水质的影响.细河与浑河中1,2-DCA的补给浓度(以ρ计)分别为4.50和6.40μgL,预测期为10 a,在运移模型中考虑弥散、吸附、降解作用的影响.模拟结果显示,预测期内1,2-DCA在细河污染区的最大影响面积为1.80 km2,峰值浓度(以ρ计)为3.50μgL,污染物向北西方向运移;在浑河污染区的最大影响面积为3.78 km2,峰值浓度为5.00μgL,污染物向西南方向运移,表明污染物对地下水水质影响程度较低.预测初期的200 d内,吸附及生物降解的共同作用使细河、浑河污染晕中心的ρ(1,2-DCA)分别下降了0.12、0.10μgL;随后,对流-弥散作用成为溶质运移的主要驱动力,并且使1,2-DCA的污染程度持续增强;黏土对1,2-DCA的运移具有阻滞作用,1,2-DCA在细河污染晕的扩散幅度略低于浑河.Serious organic contamination was surveyed in the middle reaches of Hunhe River by assessing the alluvial fan for groundwater pollution. In order to investigate the migration regularity and impact factors of organic contaminants in the regional groundwater and to predict the degree of water pollution, the migration model of characteristic components of 1,2-dichloroethane ( 1,2-DCA) was established by numerical simulation method. We analyzed the migration regularity of 1,2-DCA in the groundwater of the middle reaches of Hunhe River and calculated the influence of water quality by 1,2-DCA. For the model, the initial recharge concentration of 1,2-DCA in Xihe River and Hunhe River were 4.50 and 6.40μg/L, respectively, with a predicted period of 10 years, considering the effect of diffusion, adsorption and degradation in numerical simulation. The results indicated that the maximum impacted area by 1,2-DCA in Xihe River was 1.80 km:, with maximum value of 3.50 μg/L in the predicted period, while the impacted area in Hunhe River pollution zone was 3.78 km2, with maximum value of 5. 00 μg/L. The results showed a minor degree of damage to the regional groundwater quality. During the first 200 days of the predicted period, the adsorption and biodegradation reduced the concentrations of 1,2-DCA in the contamination halo centers in Xihe and Hunhe rivers by 0. 12 and 0. 10 μg/L, respectively. Then, with the convection-dispersion as driving force for migration, the contamination of 1,2-DCA increased continuously. Due to the retardation of the cohesive soil to the migration of 1,2-DCA, the diffusion of the contaminants in Xihe River may be slower than that in Hunhe River.
关 键 词:浑河中游 地下水 数值模拟 1 2-二氯乙烷 运移规律
分 类 号:X53[环境科学与工程—环境工程]
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