氢氧化钠催化过氧化氢异丙苯分解研究  

Study on Cumene Hydroperoxide Decomposition Catalyzed Sodium Hydroxide

作　　者：马翔[1,2] 王犇 姜杰[2] 

机构地区：[1]青岛科技大学环境与安全工程学院,山东青岛266042 [2]中国石油化工股份有限公司 青岛安全工程研究院,山东青岛266071

出　　处：《广州化工》2013年第20期36-38,共3页GuangZhou Chemical Industry

基　　金：国家科技支撑计划课题(2012BAK13B00)

摘　　要：为研究过氧化氢异丙苯(CHP)的热稳定性,本文利用C600微型量热仪对CHP和CHP与NaOH的混合物在空气中受热分解的反应和放热特性进行了实验研究。同时通过GC/MS分析了CHP和不同浓度NaOH混合后的产物组成,并利用气相色谱仪对各产物进行了定量分析,结果得出高浓度氢氧化钠催化CHP分解产物主要是2-苯基-2-丙醇,低浓度时的主要产物是乙酰苯。氢氧化钠催化CHP分解产物的组成与其浓度相关。In order to study the influence of sodium hydroxide on the thermal hazard of cumene hydroperoxide （CHP）, the thermal decomposition of CHP and CHP mixtures with different content of sodium hydroxide in the air was studied by C600 Calorimeter. CHP reacted with various concentrations of dilute sodium hydroxide as a catalyst to cleave at ambient and decomposition temperature. The products were verified by GC/MS, and were quantitatively analyzed by chromatography. CHP cleaved heterolytic with high concentrations of dilute sodium at 30 - 260 ~C, whose major product was dimethylphenyl （DMPC）. However, the main products became acetophenone by cleaved hemolytic pathway. The catalytic concentrations of NaOH significantly affected the composition products of reactions of cumene hydroperoxide mixed with sodium hydroxide.

关 键 词：过氧化氢异丙苯 氢氧化钠 热稳定性 热分解 

分 类 号：X973[环境科学与工程—安全科学]