金鸡纳生物碱-丙烯酸甲酯共聚物及其水解型聚合物的合成  

Synthesis of Poly(Cinchona alkaloid-co-methyl acrylate)s and Their Hydrolysates for Asymmetric Hydrogenation

作　　者：姜鹏[1] 吕士杰[1] 

机构地区：[1]中国科学院兰州化学物理研究所

出　　处：《应用化学》2000年第6期639-641,共3页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金资助项目!(2 99330 5 0)

摘　　要：The title copolymers and their water soluble carboxylates were synthesized from methyl acrylate and cinchonine, quinine in CHCl 3, respectively, using azo-bis- isobutyroni- trile as initiator. The four compounds as chiral amine ligands being reacted with dimethylglyoximatocobalt(Ⅱ) gave four complexes, which were used for catalytic asymmetric hydrogenation of acetamidocinamic acid, giving considerably possitive results.The title copolymers and their water soluble carboxylates were synthesized from methyl acrylate and cinchonine, quinine in CHCl 3, respectively, using azo-bis- isobutyroni- trile as initiator. The four compounds as chiral amine ligands being reacted with dimethylglyoximatocobalt(Ⅱ) gave four complexes, which were used for catalytic asymmetric hydrogenation of acetamidocinamic acid, giving considerably possitive results.

关 键 词：丙烯酸甲酯 金鸡纳生物碱 水解型聚合物 共聚物 

分 类 号：O631.5[理学—高分子化学] O629.3[理学—化学]