碳糊电极吸附伏安法测定痕量锑的研究  

Determination of Trace Antimony by Adsorptive Stripping Voltammetry at Carbon Paste Electrodes

作　　者：郭会时[1] 李益恒[2] 谢红旗[2] 

机构地区：[1]广东省韶关大学化学系,韶关512005 [2]湘潭大学化学系,湘潭411105

出　　处：《分析试验室》2000年第6期39-42,共4页Chinese Journal of Analysis Laboratory

基　　金：湖南省教委科学基金!资助项目 ( 98B0 0 7)

摘　　要：利用液体石蜡作粘合剂制成 CPE,根据锑与茜素络合剂生成的络合物在 CPE上的吸附特性 ,考察了最佳底液条件 ,共存离子的影响 ,测定了电活性络合物的组成 ,探讨了电极反应机理。方法已用于水样中锑的测定。检出限为 4×1 0 -9mol/L。An adsorptive stripping voltammetric method was developed for determination of antimony(Ⅲ) at carbon paste electrodes. The analysis procedure consisted of accumulation step at -0.20V( vs .SCE) in stirred formate buffer solution(pH 4.0) containing alizarin complex reagent, and determination step in which the antimony(Ⅲ) was measured by anodic stripping volammetry after cathodic reduction at -0.50 V in HCl solution. The peak potential was at about 0V. The concentration of antimony(Ⅲ) was linearly proportional to the second order derivative peak height over the range from 8.0×10 -9 to 8.0×10 -7 mol/L with detection limit of 4×10 -9 mol/L . The mechanism of electrode reaction was also discussed. The proposed method was applied to determination of antimony(Ⅲ) in water samples with satisfactory results.

关 键 词：锑 茜素络合剂 碳糊电极 吸附伏安法 测定 

分 类 号：O614.531[理学—无机化学] O657.1[理学—化学]