氨功能化的MCM-41催化丙二腈与α,β-不饱和酮的Michael加成  

Michael Addition Reaction of Malononitrile and α,β-Unsaturated Ketones Catalyzed by Amine Functionalized MCM-41

作　　者：王长春 谢绍雷[1] 解正峰[1] 惠永海[1] 

机构地区：[1]石油天然气精细化工教育部&新疆维吾尔自治区重点实验室新疆大学化学化工学院,乌鲁木齐830046

出　　处：《有机化学》2013年第11期2391-2395,共5页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(Nos.21162026;20962018;20862015)资助项目~~

摘　　要：利用氨功能化的MCM-41催化了丙二腈与α,β-不饱和酮的Michael加成反应,甲醇作溶剂,常温下反应产率高达99%,同时得到了一系列高产率的氰基类衍生物,催化剂具有合成简单、环境友好、多次循环利用等特点.Michael addition reaction of α, β-unsaturated ketones and malononitrile that catalyzed by amine functionalized MCM-41 in methanol afforded a series of cyano derivatives with high yield （up to 99%）. The products were afforded at room temperature. Moreover, the catalyst was also found to easiness to handle up, friendly environment, and excellent recyclability.

关 键 词：氨功能化MCM-41 Α Β-不饱和酮 丙二腈 催化 MICHAEL加成 

分 类 号：O621.25[理学—有机化学]