一种2,2'-联咪唑化合物的水热合成和晶体结构（英文）  

SOLVOTHERMAL PREPARATION AND CRYSTAL STRUCTURE OF A 2,2'-BIIMIDAZOLE COMPOUND

作　　者：陈文通[1,2] 匡汉茂[1,2] 陈华龙[1,2] 

机构地区：[1]井冈山大学应用化学研究所,江西吉安343009 [2]井冈山大学化学化工学院,江西吉安343009

出　　处：《井冈山大学学报（自然科学版）》2013年第5期19-22,共4页Journal of Jinggangshan University (Natural Science)

基　　金：The science and technology project of Jiangxi Provincial Department of Education(GJJ11535)

摘　　要：通过溶剂热反应法合成了一种2,2'-联咪唑化合物(H3O)(2,2'-biimidazole)Cl(1),并对该化合物进行了X-射线单晶结构分析。标题化合物属于单斜晶系的C2/m空间群,晶胞参数如下:a=16.5760(4),b=11.5546(4),c=4.6180(1),β=96.382(2)°,V=879.00(4)3,C6H9ClN4O,Mr=188.62,Dc=1.425 g/cm3,S=1.022,μ(MoKα)=0.393 mm-1,F(000)=392,R=0.0454和wR=0.1298。该化合物具有二维超分子结构。该化合物能够发出蓝色荧光。A biimidazole-containing compound, （H30）（2,2＇-biimidazole）C1 （1）, has been obtained through solvothermal reactions and structurally characterized by single-crystal X-ray diffraction. Compound 1 crystallizes in the space group C2/m of the monoclinic system with four formula units in a cell： a = 16.5760（4）, b = 11.5546（4）, c = 4.6180（1） A, [3 = 96.382（2）°, V = 879.00（4） A3, C6H9C1N40, Mr = 188.62, De = 1.425 g/cm3, S = 1.022, ix（MoKct） = 0.393 mm-1, F（000） = 392, R = 0.0454 and wR = 0.1298. Compound 1 is characteristic of a 2-D supramolecular layer motif. Compound 1 displays an emission in the blue region.

关 键 词：联咪唑 晶体 荧光 溶剂热 超分子 

分 类 号：O641[理学—物理化学]