高效还原剂双(2-甲氧基乙氧基)二氢铝钠  

Sodium Dihydrobis-(2-metoxyethoxy) Aluminate,an Efficient Reduction Agent

作　　者：赵开荣[1] 王芳[2] 丁克鸿[1] 

机构地区：[1]江苏扬农化工集团有限公司,江苏扬州225009 [2]扬州工业职业技术学院,江苏扬州225127

出　　处：《广东化工》2013年第21期102-103,共2页Guangdong Chemical Industry

摘　　要：简要介绍了双(2-甲氧基乙氧基)二氢铝钠(SMEAH)可能存在的两种结构以及与其它催化剂的应用比较。结果表明:SMEAH溶解性好、立体选择性高、反应条件温和,可广泛应用于不同的还原反应,在有机合成中有着巨大的应用潜力。In the paper, two possible structures of sodium dihydrobis - （2-metoxyethoxy） aluminate （SMEAH） were briefly described, and which were compared with others＇ catalyst in the application. It was found that SMEAH present excellent solubility, high stereoselectivity and mild reaction condition. SMEAH was potential applied in organic synthesis, due to general application of different reduction reactions.

关 键 词：双(2-甲氧基乙氧基)二氢铝钠 还原剂 红铝 

分 类 号：O621.2[理学—有机化学]